Document Type : Research Article
Authors
Department of Chemistry, Faculty of Applied Sciences, Durban University of Technology, Durban 4001, South Africa
Abstract
A simple and efficient procedure for the preparation of boron nitride bound N-propyl triethylenetetramine sulfonic acid (BN-BPTETSA) by the reaction of boron nitride bound N-propyl triethylenetetramine (3-TETANP BN) with chlorosulfonic acid in chloroform is described. The boron nitride (BN) nanomaterial was prepared by first activating BN with nitric acid under reflux for 24h. Thereafter trimethoxy -3-mercaptopropylchloride was added, refluxed for 24 h then an excess of triethylenetetramine was added in anhydrous xylene and the system was refluxed. After filtration and washing of the filter cake with xylene, chlorosulfonic acid was added drop-wise at 0 °C over a period of 3 h. Further filtration yielded a solid cake which was washed with ethanol and air died. The morphological properties of catalyst was characterized by FT-IR, XRD, TEM, SEM, BET and Raman spectroscopy techniques. The preparation of the catalyst is safe and demonstrates high catalytic activity for the synthesis of piperazinyl quinolinyl carbaldehyde derivatives. Furthermore, a small amount of catalyst was used, demonstrated good reusability and may have potential for industrial applications in the future. Copyright © 2018 VBRI Press.
Keywords
Appl.Phys. Lett.2004, 84, 2527-2529.
DOI:10.1063/1.1691189
2.Chen, Y.; Zou, J.; Campbell, S. J.; Le Caer, G. Appl. Phys. Lett.
2004,84, 2430-2432.
DOI:10.1063/1.1667278
3.Blasé, X. Rubio, A. Louie, S.G. Cohen, M.L. Phys. Rev. B1995,
51,6868-6875.
DOI:10.1103/PhysRevB.51.6868
4. Terrones, M.; Romo-Herrera, J. M.; Cruz-Silva, E.; López-Urías,
F.;Muñoz-Sandoval, E.; Velázquez-Salazar, J. J.; Terrones, H.;
Bando, Y.;Golberg, D. Mater.Today. 2007, 10, 30-38.
DOI:10.1016/S1369-7021(07)70077-9
5. Ciofani, G.; Raffa, V.; Menciassi, A.; Cuschieri, A.; Nano Today.
2009,4, 8-10.
DOI:10.1016/j.nantod.2008.09.001
6. Zhi, C.; Bando, Y.; Tang, C.; Golberg, D. J. Am. Chem. Soc.
2005,127, 17144-17145.
DOI:10.1021/ja055989+
7.Zhi, C.; Bando, Y.; Wang, W.; Tang, C.; Kuwahara, H.; Golberg,
D.Chem. Asian J.2007, 2, 1581-1585.
DOI:10.1002/asia.200700246
8.Ciofani, G. Expert Opin. Drug Deliv.2010, 7, 889-893.
DOI:10.1517/17425247.2010.499897
9.Zhi, C.; Hanagata, N.; Bando, Y.; Golberg, D. Chem. Asian J.
2011, 5,2530-2535.
DOI:10.1002/asia.201100114
10.Zhi, C.; Bando, Y.; Tang, C.; Xie, R.; Sekiguchi, T.; Golberg, D.
J.Am. Chem. Soc.2005, 127, 15996-15997.
DOI:10.1021/ja053917c
11.Zhi, C.; Bando, Y.; Tang, C.; Golberg, D. Mater. Sci. Eng. R
2010, 70,92-111.
DOI:10.1016/j.mser.2010.06.004
12. Chen, X.; Wu, P.; Rousseas, M.; Okawa, D.; Gartner, Z.; Zettl,
A.;Bertozzi, C.; R. J. Am.Chem. Soc.2009, 131, 890-891.
DOI:10.1021/ja807334b
13.Ciofani, G.; Raffa, V.; Menciassi, A.; Cuschieri, A. Biotechnol.
Bioeng.2008,101, 850-858.
DOI:10.1002/bit.21952
14.Ciofani, G.; Danti, S.;Alessandro, D. D.; Moscato, S.; Menciassi,
A.Biochem. Bioph.Res. Commun.2010, 394, 405-411.
DOI:10.1016/j.bbrc.2010.03.035
15. Gianni, C.; Giada, G.; Ioannis, L.; Athanassia, A.; Dinuccio, D.;
Federica, C.; Virgilio, M. Journal of Colloid and Interface
Science.2012, 374,308-314.
DOI:10.1016/j.jcis.2012.01.049
16. Zhi, C.; Bando, Y.; Wang, W.; Tang, C.; Kuwahara, H.; Golberg,
D. J.Phys. Chem. C2007, 111, 18545-18549.
DOI:10.1021/jp076980s
17. Ikuno, T.; Sainsbury, T.; Okawa, D.; Frechet, J. M. J.; Zettl, A.
SolidState Commun.2007, 142, 643-646.
DOI:10.1016/j.ssc.2007.04.010
18. Tang, C. C.; Bando, Y.; Huang, Y.; Yue, S. L.; Gu, C. Z.; Xu, F.
F.;Golberg, D. J. Am. Chem. Soc.2005, 1276552-6553.
DOI:10.1021/ja042388u
19.Zhi, C.; Bando, Y.; Terao, T.; Tang, C. C.; Kuwahara, H.;
Golberg, D.Chem. Asian J.2009, 4, 1536–1540.
DOI:10.1002/asia.200900158
20. Valentini, L.; Macan, J.; Armentano, I.; Mengoni, F.; Kenny, J.
M.Carbon. 2006, 44, 2196–2201.
DOI:10.1016/j.carbon.2006.03.007
21.Linbo, S.; Liyi, S.; Xuheng, L.; Na, S.; Peng, D. Comp Sci Tech,
2016,135, 83-91.Composites Science and Technology 135
(2016) 83-91
DOI:10.1016/j.compscitech.2016.09.013
22. Kai, W.; Chuxin, L.; Weixing, Y.; Songgang, C.; Feng, C.;
Qiang, F.Comp Sci Tech, 2016, 134, 191-200.Composites
Science andTechnology 134 (2016) 191-200
DOI:10.1016/j.compscitech.2016.08.015
23.Kiho, K.; Jooheon, K. Comp Sci Tech, 2016, 134, 209-216.
Composites Science and Technology 134 (2016) 209-216
DOI:10.1016/j.compscitech.2016.08.024
24.Arul, M.; Gengan, R. M.; Anand, K. Advanced Materials
Letters.2017, 8, 128-135.
DOI:10.5185/amlett.2017.7040
25. Arul, M.; Gengan, R. M.; Anand, K. J. MatChem Phys.2017,
188, 154-167.
DOI:10.1016/j.matchemphys.2016.12.039
)