Authors

Key Laboratory for Specially Functional Polymeric Materials and Related Technology, East China University of Science & Technology, Ministry of Education, Shanghai, 200237, China

Abstract

A Si-containing arylether arylacetylene resin, poly(dimethylsilyene-ethynylene-phenyleneetherene-ethynylene) (PSEE), was synthesized from diethynyldiphenyl ether and dichlorosilane through Grignard reactions. The structures and properties of PSEE resin were characterized by NMR, FT-IR, DSC, TGA analysis techniques. PSEE resin can be crosslinked to form a thermoset at a temperature less than 2000C. There is no glass transition in the temperature range of RT~5000C and Td5 is 5680C in N2 for PSEE thermoset. The thermoset shows good dielectric properties and its glass fiber reinforced composite exhibits high mechanical properties. Copyright © 2017 VBRI Press.

Keywords

1.FHuangandYZhou,AdvancedResinMatrixComposites(in
Chinese),
Beijing:ChemicalIndustryPress,2018,pp1-409.
2.
MItoh,MMitsuzuk,TUtsumi,etal.,J.Organomet.Chem.,476,
C30
-C31(1994).
3.
PBuvat,FJousse,LDelnaud,etal.,Int.SAMPESymposiumand
Exhibition
,46(MaterialsandProcesses),134-144(2001).
4.
MItoh,MMitsuzuk,KIwata,etal.,Macromolecules,27,
7917
-7919(1994).
5.
MItoh,KInoue,KIwata,etal.,J.Adv.Mater.,9,
1187
-1190(1997).
6.
MKKolel-Veetil,HWBeckham,TMKeller,etal.,J.Chem.
Mater.
,16,3162-3167(2004).
7.
CLHomrighausen,andTMKeller,J.Polym.Sci.:PartA:
Polym.Chem.,
40,88-94(2002).
8.
RCorriu,PGerbier,CGuerin,etal.,J.Orgaomet.Chem.,449,
111
-118(1993).
9.
OJoji,STomohisa,andKAtsutaka,Macromolecules.33,
8890
-8893(2000).
10.
MItoh,KIwata,MMitsuzuka,etal.,Macromolecules,30,
694
-701(1997).
11.
MItoh,KInoue,NHirayama,etal.,J.Mater.Sci.,37,3795-3801
(2002).

12.
HYan,HQi,andFHuang,Petro.Tech.,33,880-884(2004).
13.
JZhang,JHuang,WZhou,FHuang,etal.,EXPRESSPolym.
Let
t.,1(12),831-836(2007).
14.
FGao,LZhang,LTang,etal.,B.Kor.Chem.Soc.,31,976-980
(2010).

15.
CWang,YJiang,YGao,YZhou,FHuang,etal.,Polym.Eng.
Sci.
,526),1301-1308(2012).
16.
YGao,YZhou,andFHuang,HighPerform.Polym.,25,445-453
(2013).

17.
QWang,JHYang,QLYuan,etal.,CIESCJ.,10,4168-4175
(2014).

18.
YZhou,FHuang,andLDu,Polym.Eng.Sci.,55,316-321(2015).
19.
YJiang,JLi,FHuang,etal.,J.Am.Ceram.Soc,97(1):310-
315(2014).

20.
FWang,JFXu,JZhang,etal.,Polym.Int.,55,1063-1068(2006).
21.
JFXu,CYWu,GQLiu,etal.,Euro.Polym.J.,43,668-672
(2007).

22.
FLi,CWang,XShen,FHuang,etal.,Polym.J.,43,
59
4-599(2011).
23.C-YMTungandPJDynes,J.Appl.Polym.Sci.,27,569-574
(1982).

24.YShen,QYuan,FHuang,etal.,ThermochimicaActa,590,
66-72(2014).

25.CATerraza,LHTagle,CContador,etal.,Polym.Bull.,71,
1101-1115(2014).