Document Type : Research Article
Authors
1 Physics Department, D. M. College of Science, Manipur University, Imphal, 795001, India
2 Department of Physics, NIT Manipur, Langol, Imphal, 795004, India
Abstract
Ni-Cu-Zn ferrites with compositional formula Ni0.8-xCuxZn0.2Fe2O4, where 0.0≤x≤0.5 in steps of 0.1 were synthesized by the citrate precursor method. The samples were subjected to final sintering at 900ᵒC for 2h after a pre-sintering at 600ᵒC for 4h. X-ray diffraction patterns confirmed the formation of single phase spinel structure. The average crystallite size was calculated using Scherrer’s formula and was found to vary from 33nm to 39nm, clearly indicating the formation of nanoparticles. The infrared spectra were recorded at room temperature for all the samples in the range of 450 cm‾1 to 4000 cm‾1 using Perkin Elmer FT-IR Spectrometer. Jahn-Teller effect emerges which can be identified through the FT-IR Spectroscopy of the samples. This phenomenon may result in useful electro and magneto- optical applications. Possible mechanism is being discussed. Copyright © 2017 VBRI Press.
Keywords
Magn. Mater., 2013, 343,86.
DOI:10.1016/j.jmmm.2013.04.079
2.Jahanbin, T.; Hasim, M.; Mantori, K. A.; J. Magn. Magn.
Mater., 2010, 322, 2684.
DOI:10.1016/j.jmmm.2010.04.008
3.Jadhav,P.A.; Devan,R.S.; Kolekar,Y.D.; Chougule, B.K.;
J. Phys. Chem. Solids, 2009,70, 396.
DOI:10.1016/j.jpcs.2008.11.019
4.Dimri, M. C.; Verma, A.; Kashyap, S. C.;Dube, D.C.; Thakur,
O.P.; Prakash,C.; Mater. Sci. Eng., B, 2006, 133, 42.
DOI:10.1016/j.mseb.2006.04.043
5.Huq, M.F.;Saha, D.K.;Ahmed, R.; Mahmood, Z.H.; J.Sci.
Res., 2013, 5, 215.
DOI:10.3329/jsr.v5i212434
6.Lee, J. D. (Eds.); Concise Inorganic Chemistry; Wiley: UK,
1996.
ISBN:978-81-265-1554-7
7.Koppel, H.; Yarkony, D.R.; Barentzen, H.(Eds.); The Jahn-
Teller Effect: Fundamentals and Implications for Physics and
Chemistry; Springer Science & Business Media: Germany,
2009.
DOI:10.1007/978-3-642-03432-9
8.Awati, V.V.; Rathod, S.M.; Mane, M.L.; Mohite, K.C.; Int.
Nano Lett., 2013, 3, 2.
DOI:10.1186/2228-5326-3-29
9.Hossain, A.A.; Rahman, M.L.; J. Magn. Magn. Mater., 2011,
323, 1956.
DOI:10.1016/j.jmmm.2011.02.031
10.Soibam, I.; Phanjoubam, S.; Prakash, C.; J. Magn. Magn.
Mater., 2009, 321, 2780.
DOI:10.1016/j.jmmm.2009.04.011
11.Raju, M.K.; Chem. Sci. Trans., 2015, 4, 138.
DOI:10.7598/cst2015.957
12.Tehrani, F.S.; Daadmehr, V.; Rezakhani, A.T.; Akbarnejad,
R.H.; Gholipour, S.; J. Supercond. Novel Magn., 2012, 25,
2449.
DOI:10.1007/s10948-012-1655-5
13.Pavia, D.L.; Lampman,G.M.; Kriz, G.S.(Eds.); Introduction
to Spectroscopy; Cengage Learning: USA, 2001.
ISBN:0-03-031961-7
14.Waldron, R.D.; Phys. Rev., 1955, 99, 1727.
DOI:10.1103/PhysRev.99.1727