Document Type : Research Article
Authors
1 Department of Chemistry, Saveetha Engineering College, Chennai, Tamilnadu 602102, India
2 Department of Chemistry, Pachaiyappa’s College, Chennai, Tamilnadu 600030, India
Abstract
This paper solely describes about novel aliphatic polymer prepared from polyethyleneglycol (PEG 400) moieties by melt poly condensation of 1, 4- cyclohexanediol and dodecanedioic acid. The structural elucidation of the polymer obtained, were thoroughly investigated by various techniques such as FTIR, NMR, DSC, TGA, XRD. The polycondensation reaction was carried out by the presence of Titanium (IV) isopropoxide as catalyst. We have also discussed about the biological properties like antioxidant and biocompatibility of the polymers with its non-toxic effect.
Keywords
P.;Siegel, B.; Frye Curran, M.;Lufkin,R.J.;Martin,P.;Guze, B.;
Magn. Reson. Med.,2001,46,58.
2.Paola Rizzarelli.; Sabrina Carroccio.;Anal. Chim. Acta,2014, 808,
18.
3.Knop, K.;Hoogenboom, R.;Fischer, D.;Ulrich Schubert,S.;
Angew. Chem. Int. Ed.,2010, 49,6288.
4.Milton, H. J.(Ed.);Poly (ethylene glycol) chemistry: Biotechnical
and biomedical applications, Plenum Publishing, New York, 1992.
5.Marija Nikolic. S.; Poleti, D.; Djonlagic, J.;European Polymer
Journal,2003,39,2183.
6.Nair,M. G.;Mishar,A. R.;Muks,M. H.;Taff,W. H.;Kesller,
J. F.;Miller,J. R.;Zhu,P.;Meinhart,J. D.;Lynm,D. G.;J.Nat.
Prod.,1989, 52,779.
7.Mark, H.;Whitby,G. S.(Ed.);Collected papers of WH Carothers
on high polymeric substances, Vol.1, New York, Interscience,
1940.
8.Margaret Marie, J.;Santhi, S.;Puvanakrishnan, R.;Nanthini, R.;
Asian J. Research Chem.,2012, 5,136.
9.JablonskaPikus,T.; Charmas, W.;Podkościelna, B.;Gawdzik, B.;
J.Appl.Polym.Sci.,2001, 82,3409.
10.Blois,M S. (Ed.);Antioxidant Determinations by the Use of a
Stable Free Radical, 1958.
11.Tan, L.;Chen, Y.;Zhou, W.; Nie, H.;Li, F.;He, X.;Polym.
Degrad.Stab.,2010, 95,1920.
)